Chloe arrived in Salem in the year 1999, having lived in an orphanage for fifteen years. She reunited with her birth mother, Nancy Wesley and they faced issues in their mother-daughter relationship.
Chloe's social life was also bad as she was bullied at school for her personality and appearance, leading to her being popularly called "Ghoul girl" by her peers.
In spite of this, she managed to form a relationship with Philip Kiriakis. Chloe, who is also an opera singer, has diverted away from her early dark image over the years. She has been married three times, two of which have ended in divorce with one being annulled. She also shares a child with her late ex-husband Daniel Jonas, Parker.